The bond will fund $2.5 billion in construction projects across the UNC system, and $600 million in projects for the state's 59 community colleges.
Danny Lineberry, spokesman for House Speaker Jim Black, said a search for committee members is already under way.
"Several people decided not to take the appointment," Lineberry said.
Lineberry added that filling the committee was just a matter of time. He would not reveal the names of candidates.
The House and Senate will each appoint three candidates.
The UNC-system Board of Governors and the state Board of Community Colleges have each appointed two members to the committee.
Jeff Davies, UNC-system vice president for finance, said he expects the committee to begin meeting soon.
"As soon as membership is appointed, I'd assume that the commission would go to work immediately," he said.
Davies said his office already is working diligently on the construction matter and will be ready to meet with the committee when it is formed.